Bauxite residue (BR) is a well promising resource for critical metals, especially scandium (Sc), a rare and expensive metal with increasing applications in advanced technology. Greek BR seems to significantly favor a commercially viable recovery of Sc combining optimized leaching and advanced separation techniques. Leaching with mineral acids emerges as the dominant selection compared to other ...
The ideal conditions for the leaching process was determined through response surface methodology (RSM) to be H3PO4 concentration of mol/L, L/S ratio of 11 mL/g and leaching temperature of 40 ...
During the Bayer process, REEs Fe, Ti and other undissolved material along with remain unchanged. As a result rare earths end up in BR with an enrichment factor of approximately 2 comparing to the initialore [3]. Therefore, the aluminum industry throughthe Bayer process concentrates the critical metals found in bauxite into bauxite residue.
The separation of the alumina from the impurities in the bauxite ore is usually accomplished by the Bayer Process. In this process the ground bauxite is leached with caustic soda (NaOH) to produce soluble sodium aluminate (NaAlO2), leaving the impurities in the insoluble residue. The aluminate solution is then decomposed producing Al (OH)3 ...
In this study, a novel process of lowtemperature sulfating roastingwater leaching is presented to extract vanadium from the bauxitetype vanadium ore. Addition of sulfuric acid enhanced the ...
Bauxite residue (BR), an alkaline industrial waste, is a major byproduct of the alumina production process known as the Bayer process. The Bayer process generates a byproduct known as bauxite residue (red mud). This residue was leached with sulfuric acid in a pilot plant of Mytilineos to recover scandium. Scandium was selectively recovered in pilotscale experiments using ion exchange.
The Bayer process is used worldwide for the alumina production. This process involves the alkaline leaching of bauxite to extract Al, followed by the precipitation of Al(OH) 3 to recycle the solution [1,2,3].The leaching process results in the formation of a solid residue, commonly referred to as a bauxite residue, which consists of iron minerals, hydrous aluminosilicates, which are formed ...
Therefore, the leaching process with dilute HNO 3 has been performed and optimized at a pilot scale for the recovery of scandium from bauxite residue . According to Petrakova et al., leaching with nitric acid could be a problem due to the absorption of nitrate ions on the residue, so that large volumes of water are needed for their removal [ 43 ].
Bauxite residue, known as red mud, is a byproduct of alumina production using the Bayer process. Currently, its total global storage amounts to over billion tons, including about 600 million ...
The lateritic bauxite hydrochloric acid leaching process showed that when the ore granularity was less than 55 μm, the liquid/solid ratio (L/S ratio) was 100:7, the leaching temperature was 373383 K, the leaching time was 120 min and the HCl concentration was 10%, both the leaching rates of Al and Fe were over 95% . But the hydrochloric ...
Experimental Method. In this study, the recovery of precious metals from bauxite ore was examined by a twostage leaching process. The stages of this process were Stage I: Removing iron to a large extent and revealing the solubility conditions of titanium by treating the bauxite ore with oxalic acid, Stage II: Determining the recovery conditions of aluminum from the residue obtained after the ...
Gibbsitic bauxite from Australia was leached by hydrochloric acid in this work. Analysis on kinetics for the extraction of Al 2 O 3 was quantitatively studied. It was concluded that the hydrochloric acid leaching process of gibbsitic bauxite was controlled by chemical reaction. Moreover, the mechanism for the dissolution followed the equation ...
Bauxite is widely used to produce alumina. There are many bauxite resources with high iron content. These resources could not be processed and utilized efficiently due to the high concentration of iron (Fe). The alkaline leaching process has been proposed to remove iron from these bauxite resources. Therefore, in this study, the alkaline leaching process was employed, and the effects of sodium ...
The Bayer process is the principal industrial means of refining bauxite to produce alumina (aluminium oxide) and was developed by Carl Josef, the most important ore of aluminium, contains only 3060% aluminium oxide (Al 2 O 3), the rest being a mixture of silica, various iron oxides, and titanium dioxide. The aluminium oxide must be further purified before it can be refined ...
In order to explore the commercialized applications of the lowgrade bauxite in the refractory industry, a calcination integrated with acid leaching method was adopted to remove the potassium (K) and iron (Fe) from the diasporeillite (DI) type lowgrade bauxite. Following calcining the bauxite at different temperatures, the leaching parameters, including the sulfuric acid concentration ...
The circulation liquid and lime (75% active CaO) for Bayer leaching were obtained from Guizhou, China. Methods. Three different AlFe recovery processes can be found in Fig. shown in Fig. 2, the LRS process means that the bauxite is firstly subjected to Bayer leaching, followed by magnetic roasting of red mud, and then, the roasted red mud would be magnetically separated for ...
An example of the leaching process would be the leaching of Al 2 O 2 O (or bauxite) with a heated and concentrated solution of sodium hydroxide. In this example, the concentrated NaOH dissolves the aluminium present in the bauxite whereas the impurities such as Fe 2 O 3, TiO 2, and SiO 2, are not dissolved by the reagent.
Thus, this process doesn't look compatible with laterite where the iron content is much higher than typical lowgrade bauxite. Hence, an alternative acid leaching extraction was planned. For any earth material extraction process, the study of the kinetic behavior of element extraction is crucial to make the process efficient.
The process of Leaching is used to concentrate the ore. NaAlO 2 + 2H 2 O → NaOH + Al(OH) 3. Serpek's process: This process is used when the bauxite ore contains a higher percentage of silica as an impurity. In this process, powdered bauxite ore is mixed with carbon (coke) and heated to 1473K in a current of nitrogen.
The research on pressure leaching started in 1887. Karl Josef Bayer was the first one who proposed to leaching bauxite with sodium hydroxide solution at a temperature of 413453 K to obtain sodium ...
The Bayer process is the main method of alumina production worldwide. The use of lowquality bauxites for alumina production results in the formation of a significant amount of technogenic waste—bauxite residue (BR). The Bayer reductive method is one possible way to eliminate BR stockpiling, but it requires highpressure leaching at temperatures higher than 220 °C.
In the process of recovering valuable elements from bauxite residue, the acid leaching process method is mainly used at present, which includes hydrochloric acid leaching, sulfuric acid leaching, nitric acid leaching, etc. Nitric acid is highly corrosive and cannot be connected with the medium of the subsequent extraction process, so most of them use hydrochloric acid or sulfuric acid leaching.
Brazil is the third largest country in the world in bauxite resources and production [1, 2].This ore is the raw material for alumina production through the Bayer process, where sodium hydroxide is used as leaching agent, which enables the selective leaching of alumina.
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